Prototype G PROBLEM STATEMENT Use MATLAB to Calculate Z and

Prototype G PROBLEM STATEMENT Use MATLAB to Calculate Z. and V for Argon at 25 °C and 35 bars by the following equations: a) The truncated virial equation with the following experimental values of virial coefficients: .2 b) The truncated virial equation, with a value of B from the generalized Pitzer correlation. c) The Redlich/Kwong equation d) The Soave/Redlich/K wong equation e) The Peng/Robinson equation.

Solution

Ans-Approximates compressibility factor (commonly denoted Z) of gas at a given temperature and absolute pressure. Calculated by Van der Waals equation of state.

Z = PV/(RT)

Solves compressibility factor for the following gases:
air
ammonia
argon
butane
carbon dioxide
carbon monoxide
methane
ethane
helium
hydrogen
neon
nitrogen
oxygen
propane
sulfur dioxide
sulfur hexafluoride

Note: The Van der Waals equation is an improvement of the ideal gas law, above the critical temperature, and is also qualitatively reasonable below the critical temperature, but it is almost never appropriate for rigorous quantitative calculations. (Paraphrased from T.L. Hill, Statistical Thermodynamics, Addison-Wesley, Reading (1960))

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Example 1: Find the compressibility factor of methane at 280 K and 20 bar:

Z = compressibility(\'methane\',280,20)
Z = 0.951

The above example shows that methane at 280 K and 20 bar deviates from the ideal gas law by approximately 4.9%.

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Example 2: Calculate Z for a range of pressures with constant temperature:

T = 195; % [°K]
P = 1:100; % [bar]

Z = compressibility(\'sf6\',T,P);

plot(P,Z)
box off
xlabel(\'hydrostatic pressure (bar)\')
ylabel(\'compressibility factor {\\it Z}\')
title([\'SF_6 at \',num2str(T),\' K\'])

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Example 3: Calculate Z for an array ofCalculate Z for arrays of simultaneously-varying pressure and temperature values.

compressibility(\'methane\',[280 300 350],[1 10 20])

ans =
    0.9976
    0.9802
    0.9755

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This function can be modified to solve for any gas you wish if you know its critical temperature Tc and critical pressure Pc. Do this by adding a case in the following form

case \'your gas\'
    Tc = YourGasTc; % [K] critical temperature
    Pc = YourGasPc; % [bar] critical pressure

Above you must enter the name of \'your gas\' and the correct values for YourGasTc and YourGasPc.

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I am not a thermodynamicist, so I can not fully attest to the accuracy of this function, or the appropriateness of using it for any given gas (including the gases listed above).