The equation of state for radiant energy in equilibrium with
The equation of state for radiant energy in equilibrium with the temperature of the walls of a cavity of volume v is p = nT^3/4. the energy equation is U = aT^3V^2/4 a and b are constants. How much heat is supplied in an isothermal tripling of the volume of the cavity? dQ = dU + PdV
Solution
U = aT3V2 /4
dU = aT3 *2VdV/4
dQ = (aT3 /2) VdV +bT3/4 dV
V changes from v to 3V and T is constant as the process is isothermal
Q = (aT3 /2)òVdv + bT3/4 òdv with limits V to 3V
= (aT3 /2) V2/2 + bT3/4 V apply limits
= (aT3 /4) ((3V)2 –V2 ) + bT3/4 (3V –V)
= 2aT3 V2 + bT3V/2
