chemical A reversible Carnot cycle operates with 10 kg of ai
Solution
solution:
1)here T S diagram is given by closed rectangle 3412. and Pv diagram is closed system with isothermal curve of PV=constant for 34 and 12 processes and PV^k=constant for 14 and 23 processes.
2)here for 3-4 process as temperature is constant hence internal energy change is zero,hence by first law of thermodynamics we get that
Q=W=mRT3ln(V4/V3)
P3/P4=V4/V3=2/4=.5
on putting value in above equation we get that
Q34=W34=10*.287*632*ln(.5)=-1257.258 KJ
3)for adaibitic process heat transfer is zero
Q41=0
W41=mCv*(T4-T1)
W41=-2642.24 Kj
5)for isothermal process 1-2 we have
P1V1=P2V2
P1/P2=V2/V1=20/10=2
Q12=W12=mRt2ln(V2/V1)
Q12=W12=1989.33 KJ
6)for adiabitic process 23 we have again heat transfer is zero
Q23=0
W23=m*Cv*(T2-T3)=2642.24 KJ
7)hence net work of system is given by
W=W23+W12+W41+W34
W=2642.56+1989.33-2642.56-1257.258
W=732.072 KJ
8)here supplied heat is while isothermal expansion,hence
Q12=1989.33 KJ
9)efficiency is ratio of net work to heat supplied
n=W/Q12=732.072/1989.33=.367999=36.799927%
10)here by formula we get efficiency as
n=1-(Tmin/Tmax)=1-(632/1000)=.368=36.8 %

