Terms A System Concept B A thermodynamic properties of fluid

Terms (A) System Concept (B) A thermodynamic properties of fluid that is a function of volume and temperature Significant effect of molecular interaction between gas ytropic molecules Energy added to a fluid as work is later transferred from the fluid as heat. Where is this energy between its addition to Residual and transfer from the fluid? An equation of state that can be used to address deviation from Ideal condition of gases only The difference between Ideal and Actual properties is One of the stages in the Carnot cycle Gauge pressure Isobaric Cv Gibbs Energy (T,P) Validating results with back substitution, order of Work Heat Pump Temperature Virial E.O.S State magnitude,test of reasonableness A measure of deviation from ideal gas conditions A good common source of irreversibility is Generating function for other thermodynamic properties A good example of a high-temperature source reservoir the mass and entropy of the fluid in the control volume are constant, and d(mS)ev/ dt is zero Heat of reaction that is involve in the reaction of elemental species of compound Three volume roots of which two may be complex 10 12 13 14 15 Thermal Reservoir 16 Quasi static Heat of formation Constant pressure process of system at Ideal condition It is impossible to construct a device that operates in a cycle and produces no effect other than the transfer of heat from a lower-temperature body to a higher-temperature body It determine the occurrence, direction and restriction of process and also determine the quality of energy and Precision 17 ormance of a system In the limit that AS-0, then the process is: 18 Steady state 19 Generalized Correlations A quantity of matter or a region in space chosen for study Enthalpy change with reactants and product at their standard state and temperature The thermodynamic concepts responsible for determining the number of properties needed to fix a thermodynamic system For two given heat Reservoirs, no engine can have thermal efficiency Higher than that of a Carnot engine Transformation of energy from one form to another is address by: Friction 21 Sensible heat 23 Turbine

Solution

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System

A quantity of matter or region in space choosen for study

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Cv

As dH/dt is Cp so is dU/dt is to

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work

As efficiency is to heat engine, so is coefficient of performance is to

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Quasi static

Process proceeds in such a manner that system remains infinitesimally close to equilibrium

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friction

A good common source of irreversibility is

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transformaton of energy from one form to another

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Super critical fluid

A fluid with temperature and pressure above critical point

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Entropy

A measure of disorderliness from microscopic point of view

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Compressibility factor

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System

A quantity of matter or region in space choosen for study

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gauge pressure difference between the absolute pressure of a system and absolute pressure of the atmosphere existing outside the measuring device

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isobaric constant pressure process of a system at ideal condition

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Cv

As dH/dt is Cp so is dU/dt is to

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gibbs energy da=-pdv-sdt

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work

As efficiency is to heat engine, so is coefficient of performance is to

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virial E.O.S AN E.O.S that can be used to address deviation from ideal condition of gases only

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Quasi static

Process proceeds in such a manner that system remains infinitesimally close to equilibrium

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da=-pda-sdt

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steady state the mass and entropy of the fluid in the control volume are constant and d(ms)cv/dt=0

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friction

A good common source of irreversibility is

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k=1/v(dp/dv) isothermal compressibility of a liquid

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real gas a measure of deviation from ideal gas conditiond

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first law

transformaton of energy from one form to another

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internal energy heat transfer to a system in which there is no phase transititions ,no chemical reactions and no changes in composition causes the temperature to change

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Super critical fluid

A fluid with temperature and pressure above critical point

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nuclear reactor

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cubic equation of state condition of a system that describe by its properties

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second law a hypothetical body with a large thermal capacity to which heat can be transferred without changing its temperature

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clausius statement it is impossible to construct a machine that operates in a cycle and produces no effect other than the transfer of heat from a lower temperature to higher temperature of a body

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Entropy

A measure of disorderliness from microscopic point of view

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Compressibility factor

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completely reversible in the limit delta s=0,
 Terms (A) System Concept (B) A thermodynamic properties of fluid that is a function of volume and temperature Significant effect of molecular interaction betwe
 Terms (A) System Concept (B) A thermodynamic properties of fluid that is a function of volume and temperature Significant effect of molecular interaction betwe
 Terms (A) System Concept (B) A thermodynamic properties of fluid that is a function of volume and temperature Significant effect of molecular interaction betwe

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