If 646 L of gaseous ethanol reacts with 161 L O2 what is the
If 6.46 L of gaseous ethanol reacts with 16.1 L O2, what is the maximum volume of gaseous carbon dioxde produced? Assume that the temperature of the reactants and products is 425 °C and the pressure remains constant at 1.00 atm.
CH3CH2OH(g) + 3 O2(g) ® 2 CO2(g) + 3 H2O(g)
6.46 L
10.7 L
12.9 L
16.1 L
22.6 L
2.
At what temperature does 742 mm Hg of CH4 gas have the same density as 742 mm Hg of O2 gas at 273 K?
137 K
146 K
191 K
275 K
545 K
3.
A 10.0 L flask at 318 K contains a mixture of Ar and CH4 with a total pressure of 1.040 atm. If the mole fraction of Ar is 0.715, what is the mass percent of Ar?
13.8%
68.8%
71.5%
82.9%
86.2%
4. Methane gas, CH4, effuses through a barrier at a rate of 0.568 mL/minute. If an unknown gas effuses through the same barrier at a rate of 0.343 mL/minute, what is the molar mass of the gas?
20.8 g/mol
28.0 g/mol
32.0 g/mol
44.0 g/mol
64.0 g/mol
5. Carbon monoxide reacts with oxygen to form carbon dioxide.
2 CO(g) + O2(g) ® 2 CO2(g)
In a 1.00 L flask, 4.30 atm of CO reacts with 2.50 atm of O2. Assuming that the temperature remains constant, what is the final pressure in the flask?
1.80 atm
2.50 atm
4.30 atm
4.65 atm
6.80 atm
Solution
1)from stoichoimetry,and as P&T remains constant
volume of Co2=12.92 litres
2)pv=nrt
n/v=p/RT
m/v=pM/RT
742*16/RT= 742*32/R*273
T=136.5K=137K
3)PV=NRT
1.040*10=0.0821*N*318
N=0.3983
mole of Ar=0.2848
moles of CH4=0.1135
so mass % of Ar= 0.2848*40/(0.2848*40 +0.1135*16) =86.25%
4)0.568/0.343=sqrt(M/16)
M=43.876=44
5)
O2 is limiting
so O2 consumed=2.15 atm
co O2 remaining=0.35 atm
CO2 produced=4.3 atm
so total pressure=4.3+.35=4.65 atm

