A certain indicator HA has a Ka value of 25105 The protonate
A certain indicator, HA, has a Ka value of 2.5×105. The protonated form of the indicator is yellow and the ionized form is red.
What is the pKa of the indicator?
What is the color of this indicator in a solution with pH = 7?
orange
yellow
red
Solution
= -log(2.5 x 10^-5)
= 4.60
Pka of indicator = 4.60
pH = pKa + log([A-]/[HA])
6 = 4.60 + log([A-]/[HA])
log([A-]/[HA]) = 1.40
[A-]/[HA] = 101.40 = 25.11
[A-] = 25.11 x [HA]
From the above equation , it is evident that the concentration of the ionized form A- is 25.11 times to the concentration of the protonated form HA.
It shows red color

