Thermodynamics in Materials Science question The excess free
Thermodynamics in Materials Science question:
The excess free energy of mixing in fcc solid solutions of aluminum and zinc is well described by the relation:
 GXS=XAlXZn(9600Xzn + 13200XAl)(1-(t/4000))
Compute and plot curves for Gmix as a function of composition for a sequence of temperatures every100K.
Please clear solution and clear handwriting. Show clear all steps!!!
Solution
free energy of mixing is defined as
delta g = delta H - T*delta S
The variation in free energy as a function of composition and temperature can be considered for three different situations an ideal solution, a non - ideal solution with a positive enthalpy of mixing and non ideal solution with negative enthalpy of mixing
for ideal solution delta H = 0
for non ideal delat H >0 or <0

