The reactants A and B are mixed and the reaction is timed un

The reactants A and B are mixed, and the reaction is timed until a color change occurs. The data are as follows:

[A]

[B]

Time (s)

0.100

0.140

25

0.050

0.140

50

0.100

0.070

100

Determine the rate law.

[A]

[B]

Time (s)

0.100

0.140

25

0.050

0.140

50

0.100

0.070

100

Solution

In the given data,

The reaction time get doubled when the [A] is halved and the reaction time increased by 4 times when [B] is halved thus the rate of reaction is first order with respect to A and second order with respect to B. Hence rate law is

r = k[A][B]^2

The reactants A and B are mixed, and the reaction is timed until a color change occurs. The data are as follows: [A] [B] Time (s) 0.100 0.140 25 0.050 0.140 50

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