Which of the following aqueous solutions should have the hig
Which of the following aqueous solutions should have the highest boiling point?
a) 0.50 m NaOH b) 1.0 m CH3CO2H c) 0.50 m CaCl2 d) 1.5 m C6H12O6 e) 1.0 m LiBr
Solution
As we know that
Elecvation in Boiling point = Kim
Here i = No. of ions which a Compound can Break
m = Molality
So for Highest Boliling Point
i*m should be Maximum
For NaOH
Product is 0.5*2
= 1
For CH3CO2H and C6H12O6 i = 1
therefore products are 1 and i.5
For CaCl2 i = 3
So Prodcut = 3*0.5
= 1.5
For LiBr i = 2
Therefore
PRODUCT = 1*2
= 2 MAXIMUM
Therefore
e option is Correct

