A 350 mL sample of 0142 M HNO2 is titrated with 0206 M KOH K

A 35.0 mL sample of 0.142 M HNO2 is titrated with 0.206 M KOH. (Ka for HNO2 is 4.57×104.)


A 35.0 mL sample of 0.142 M HNO2 is titrated with 0.206 M KOH. (Ka for HNO2 is 4.57×104.)


A 35.0 mL sample of 0.142 M HNO2 is titrated with 0.206 M KOH. (Ka for HNO2 is 4.57×104.)



Solution

HNO2 = 35.0ml of 0.142M

number of moles of HNO2= 0.142Mx0.035L= 0.00497 moles

KOH= 0.206M

volume of KOH = 0.142x35.0/0.206 = 24,13ml

number of moles of KOH= 0.206Mx0.02413L = 0.00497 moles

Ka = 4.57x10^-4

-log(Ka) = -log(4.57x10^-4)

PKa= 3.34

It is the equivalent point

so at equivalent point

PH= 7 + 1/2[PKa + logC]

C= number of moles/volume

total volume= 35.0 + 24.13 = 59.13 ml = 0.05913L

C= 0.00497/0.05913 = 0.084M

PH= 7 + 1/2[ 3.34+ log(0.084)]

PH= 8.13

 A 35.0 mL sample of 0.142 M HNO2 is titrated with 0.206 M KOH. (Ka for HNO2 is 4.57×104.) A 35.0 mL sample of 0.142 M HNO2 is titrated with 0.206 M KOH. (Ka fo

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