Why must Group IV be treated with NH42CO3 in basic solution

Why must Group IV be treated with (NH4)2CO3 in basic solution? What would happen if the solution were acidic when the sodium carbonate was added?

Solution

It is added to introduce the common ion effect which reduces the solubility product of the other group elements

If (NH4)2CO3 then every element from that group will get precipitated.

Why must Group IV be treated with (NH4)2CO3 in basic solution? What would happen if the solution were acidic when the sodium carbonate was added?SolutionIt is a

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