Order the following stationary phaases by degree of polarity
Order the following stationary phaases by degree of polarity from low (#1 least polar) to high (#5 most polar):
a) 90% Bis-cyanopropyl 10% cyanopropyl phenyl polysiloxane
b) 5% Phenyl 95% dimethyl polysiloxane
c) Carbowax
d) 100% dimethyl polsiloxane
e) 14% cyanopropyl phenyl, 86% polysiloxane
Solution
a) 90% Bis-cyanopropyl 10% cyanopropyl phenyl polysiloxane ----- mid/high polarity
b) 5% Phenyl 95% dimethyl polysiloxane ---- non-polar
c) Carbowax - moderately polar
d) 100% dimethyl polsiloxane - non-polar
e) 14% cyanopropyl phenyl, 86% polysiloxane - low/mild polarity
So, the given stationary phases can be ordered by degree of polarity from low (#1 least polar) to high (#5 most polar) as :
#1 - d) 100% dimethyl polsiloxane
#2 - b) 5% Phenyl 95% dimethyl polysiloxane
#3 - e) 14% cyanopropyl phenyl, 86% polysiloxane
#4 - c) Carbowax
#5 - a) 90% Bis-cyanopropyl 10% cyanopropyl phenyl polysiloxane
