Stoichiometry 2 For the given combustion reaction of octane
Solution
Part a
Five molar ratios are
O2/C8H18 = 25/2 = 12.5
CO2/C8H18 = 16/2 = 8
H2O/C8H18 = 18/2 = 9
CO2/O2 = 16/25 = 0. 64
H2O/O2 = 18/25 = 0.72
Part b.
From the stoichiometry of the reaction
Excess reactant = O2
Limiting reactant = C8H18
2 mol of C8H18 produces = 16 mol of CO2
0.67 mol of C8H18 produces = 16*0.67/2 = 5.36 mol of CO2
Moles of CO2 formed = 5.4 mol
Part C
From the stoichiometry of the reaction
Excess reactant = O2
Limiting reactant = C8H18
2 mol of C8H18 produces = 18 mol of H2O
0.67 mol of C8H18 produces = 18*0.67/2 = 6.03 mol of H2O
Moles of H2O formed = 6 mol
Part d
Moles of C8H18 = mass/molecular weight
= 225g / (8*12+18*1) g/mol
= 1.9736 mol
From the stoichiometry of the reaction
2 mol of C8H18 reacts with = 25 mol of O2
1.9736 mol of C8H18 reacts with = 25*1.9736/2 = 24.67 mol of O2
Moles of O2 required = 24.7 mol
Part e
From the stoichiometry of the reaction
Excess reactant = O2
Limiting reactant = C8H18
2 mol of C8H18 produces = 16 mol of CO2
1.9736 mol of C8H18 produces = 16*1.9736/2 = 15.78 mol of CO2
Moles of CO2 formed = 15.8 mol

