How many photons at 553 nm must be absorbed to melt 380 102
How many photons at 553 nm must be absorbed to melt 3.80 × 102 g of ice? (Hint: It takes 334 J to melt 1 g of ice at 0°C.) Enter your answer in scientific notation. 3.54 × 10 23 photons On average, how many H2O molecules does one photon convert from ice to water? molecules
Solution
1)
 1st calculate the heat required to melt all ice
 Q = mass * Hfus
 = 3.80*10^2 g * 334 J/g
 = 1.27*10^5 J
 Given:
 lambda = 5.53*10^-7 m
 1st calculate energy of 1 photon
 
 use:
 E = h*c/lambda
 =(6.626*10^-34 J.s)*(3.0*10^8 m/s)/(5.53*10^-7 m)
 = 3.595*10^-19 J
 
 number of photon = total energy/energy of 1 photon
 n = (1.27*10^5)/3.595*10^-19
 = 3.53*10^23
 Answer: 3.53*10^23 photons
2)
 
 Molar mass of H2O,
 MM = 2*MM(H) + 1*MM(O)
 = 2*1.008 + 1*16.0
 = 18.016 g/mol
 
 
 mass(H2O)= 380 g
 
 use:
 number of mol of H2O,
 n = mass of H2O/molar mass of H2O
 =(380.0 g)/(18.016 g/mol)
 = 21.09 mol
 use:
 number of molecules = number of mol * Avogadro’s number
 number of molecules = 21.09 * 6.022*10^23 molecules
 number of molecules = 1.27*10^25 molecules
number of molecules per photon = number of molecules/number of photon
 = (1.27*10^25)/(3.53*10^23)
 = 36.0
 Answer: 36 molecules

