A voltaic cell consists of an AlAl3 halfcell and a AgAg half
A voltaic cell consists of an Al/Al3+ half-cell and a Ag/Ag+ half-cell. Calculate Ecell when [Ag+] = 0.00160 M and [Al3+] = 0.9040 M.
You should use the reduction potentials for Al3+ is -1.66 V and for Ag+ is 0.80 V.
Solution
Al + 3Ag+ --->Ag(s) +Al3+
so Eo=0.8+1.66
=2.46 V
so,
E=Eo-0.059/3 log([Al+]/[Ag3+]^3)
=2.46 -(0.059/3) * log(0.904/(0.0016^3))
=2.2959 V
![A voltaic cell consists of an Al/Al3+ half-cell and a Ag/Ag+ half-cell. Calculate Ecell when [Ag+] = 0.00160 M and [Al3+] = 0.9040 M. You should use the reduct A voltaic cell consists of an Al/Al3+ half-cell and a Ag/Ag+ half-cell. Calculate Ecell when [Ag+] = 0.00160 M and [Al3+] = 0.9040 M. You should use the reduct](/WebImages/44/a-voltaic-cell-consists-of-an-alal3-halfcell-and-a-agag-half-1139351-1761610703-0.webp)