Why does the compound CoCl26H2O turn blue when dissolved in
Why does the compound CoCl2*6H2O turn blue when dissolved in ethanol and pink when dissolved in water?
Solution
Co(II) forms two colored complexes with Cl- ions that exists in the following equilibrium,
[Co(H2O)6]2+(aq) + 4Cl- (aq) ---->[CoCl4]2- (aq)+6H2O(l)
[Co(H2O)6]2+(aq),pink color exists in water,while [CoCl4]2- ,(blue) dominates in ethanol
In ethanol ,[CoCl4]Cl2 form ,while in water [Co(H2O)6]Cl2 is formed
